<em>n</em>-Pentane Isomerization under Supercritical Conditions over Pt-Modified Solid Acid Catalysts Статьи журнала «Сверхкритические Флюиды: Теория и Практика»

2007, №4

сс. 60-69

V.I. Bogdan, A.E. Koklin, V.B. Kazansky

Key words: supercritical n-pentane, catalytical isomerization, zeolite catalysts

The study of n-pentane isomerization under supercritical conditions over unmodified and Pt-modified acid catalysts (WO₃- and H₄[Si(W₃O₁₀)₄]-loaded TiO₂, different types of zeolites) was carried out in continuous flow reactor in the range of temperature 220÷350 °С and pressure 50÷130 atm, liquid hourly space velocity was varied between 6 and 30 h^-1. Base acid catalysts were either not active (WO₃/TiO₂), or subjected to quick deactivation (H₄[Si(W₃O₁₀)₄]/TiO₂). Their platinum modification leads to dramatic increase of total conversion up to 50% and to decrease of poison rate during 3÷5 hours. The most active and selective catalyst for n-pentane isomerization under supercritical conditions among examined zeolites systems was H-form of mordenite, but platinum modification decreases the catalyst activity. Process of cracking was prevailing over H-ZSM-5, but its modification with platinum leads to gain of iso-pentane yield.
Key words: supercritical n-pentane, catalytical isomerization, zeolite catalysts.

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ГОСТ
7.0.100-2018

Богдан, В.И. n-Pentane Isomerization under Supercritical Conditions over Pt-Modified Solid Acid Catalysts / В.И. Богдан, А.Е. Коклин, В.Б. Казанский. – Текст : непосредственный // Сверхкритические Флюиды: Теория и Практика.. – 2007. – Т. 2. – № 4. – С. 60-69.

TRANSLIT

Bogdan, V.I. Izomerizaciya n-pentana v sverhkriticheskih usloviyah na modificirovannyh platinoj tverdokislotnyh katalizatorah / V.I. Bogdan, A.E. Koklin, V.B. Kazanskij. – Sverhkriticheskie Flyuidy: Teoriya i Praktika.. – 2007. – Т. 2. – № 4. – S. 60-69.

V.I. Bogdan, A.E. Koklin, V.B. Kazansky n-Pentane Isomerization under Supercritical Conditions over Pt-Modified Solid Acid Catalysts. Sverhkriticheskie Flyuidy: Teoriya i Praktika, 4, 60-69 (2007). https://doi.org/

n-Pentane Isomerization under Supercritical Conditions over Pt-Modified Solid Acid Catalysts

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