Catalytic oxidative coupling of dimethyl ether in supercritical conditions

2012, №3

сс. 69-73

V.I. Bogdan, A.L. Kustov, L.M. Glukhov, A.N. Kalenchuk, L.M. Kustov, I.P. Beletskaya

Key words: supercritical fluid, catalytic oxidation, dimethyl ether, monoglim

For the first time the reaction of catalytic oxidative coupling of dimethyl ether (DME) in supercritical conditions is investigated. Oxidation of dimethyl ether by molecular oxygen in the presence of a СаO—SnO₂ catalyst was carried out in the medium of excess reactant (DME) and in its mixtures with carbon dioxide in supercritical (SC) conditions (100 atm, 250—300 °C). At 255 °C a maximum conversion of DME (approaching 40 % at monoglim: diglim ratio about 2:1) is reached at 20-fold (by volume) dilution of DME with SC-CO₂.

Translated article

doi:10.1134/S1990793113070051

Предыдущая статья Следующая статья

Цитировать

ГОСТ
7.0.100-2018

Богдан, В.И. Catalytic oxidative coupling of dimethyl ether in supercritical conditions / В.И. Богдан, А.Л. Кустов, Л.М. Глухов [и др.]. – Текст : непосредственный // Сверхкритические Флюиды: Теория и Практика.. – 2012. – Т. 7. – № 3. – С. 69-73.

TRANSLIT

Bogdan, V.I. Kataliticheskaya okislitel'naya kondensaciya dimetilovogo efira v sverhkriticheskih usloviyah / V.I. Bogdan, A.L. Kustov, L.M. Gluhov [i dr.]. – Sverhkriticheskie Flyuidy: Teoriya i Praktika.. – 2012. – Т. 7. – № 3. – S. 69-73.

V.I. Bogdan, A.L. Kustov, L.M. Glukhov, A.N. Kalenchuk, L.M. Kustov, I.P. Beletskaya Catalytic oxidative coupling of dimethyl ether in supercritical conditions. Sverhkriticheskie Flyuidy: Teoriya i Praktika, 3, 69-73 (2012). https://doi.org/

Catalytic oxidative coupling of dimethyl ether in supercritical conditions

Цитировать

Спасибо. Ваши данные отправлены