Allylic Substitution in Supercritical Carbon Dioxide Medium Catalyzed by Palladium Complexes with Phosphite-type Ligands

2011, №2

сс. 27-34

S.E. Lyubimov, T.A. Verbitskaya, E.A. Rastorguev, P.V. Petrovskii, V.N. Kalinin, V.A. Davankov.

Key words: supercritical carbon dioxide, allylic substitution, palladium complexes, phosphites, regioselectivity

Allylic amination and alkylation catalyzed by Pd complexes is carried out in supercritical carbon dioxide (SC-СO₂) using phosphite-type ligands. It is shown that Pd-catalysts dissolved in SC-СO₂ provide a high regioselectivity and thus present a useful approach to the synthesis of allylamines.

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ГОСТ
7.0.100-2018

Любимов, С.Е. Allylic Substitution in Supercritical Carbon Dioxide Medium Catalyzed by Palladium Complexes with Phosphite-type Ligands / С.Е. Любимов, Т.А. Вербицкая, Е.А. Расторгуев [и др.]. – Текст : непосредственный // Сверхкритические Флюиды: Теория и Практика.. – 2011. – Т. 6. – № 2. – С. 27-34.

TRANSLIT

Lyubimov, S.E. Kataliziruemoe kompleksami palladiya allil'noe zameshchenie v srede sverhkriticheskogo dioksida ugleroda s uchastiem ligandov fosfitnogo tipa / S.E. Lyubimov, T. A. Verbickaya, E.A. Rastorguev [i dr.]. – Tekst : neposredstvennyj // Sverhkriticheskie Flyuidy: Teoriya i Praktika.. – 2011. – Т. 6. – № 2. – S. 27-34.

S.E. Lyubimov, T.A. Verbitskaya, E.A. Rastorguev, P.V. Petrovskii, V.N. Kalinin, V.A. Davankov Allylic Substitution in Supercritical Carbon Dioxide Medium Catalyzed by Palladium Complexes with Phosphite-type Ligands. Sverhkriticheskie Flyuidy: Teoriya i Praktika, 2, 27-34 (2011). https://doi.org/

Allylic Substitution in Supercritical Carbon Dioxide Medium Catalyzed by Palladium Complexes with Phosphite-type Ligands

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