2015, №1

pp. 78-85

Phase Equilibria in the System LiOH—H2O at 350—425 °C

2015, №1

сс. 78-85

Quote

M.A. Urusova, V.M. Valyashko.

Key words: phase diagrams, solubility, liquid-liquid immiscibility, critical phenomena

The system LiOH—H2O is characterized by the immiscibility phenomena both in equilibrium with vapor and solid saturated solutions or without solid phase. Solubility of LiOH increases as a result of immiscibility phenomena at ∼355 °С and further increases above this temperature up to the melting point. The immiscibility region (g - l1 - l2) is terminated by the critical phenomena (g = l1 - l2) at ∼390 °С. A separation of liquid phases is observed at elevated pressures (at ∼39 MPa) and temperatures up to 425 °C.