2018, №4

pp. 36-40

Problem of Loss of Active Metal in the Process of SC-CO2 Extractional Regeneration of the Hydro-Cleaning Catalyst

2018, №4

сс. 36-40

Quote

T.R. Bilalov, F.M. Gumerov.

Key words: Co-Ni-Mo catalyst, hydrotreating, hydrogenation, extraction regeneration, supercritical carbon dioxide

In the course of studying the peculiarities of regeneration of the hydrodesulfurization catalyst DN-3531 in the supercritical CO2 media it was shown that nickel oxide does not dissolve in it. However, in the case of application of a mixture of CO2+DMSO (5% mass) in the specified conditions, dissolution of nickel oxide in supercritical fluid solvents appears as possible due to the formation of Ni[DMSO]xOHy complex, which is soluble in supercritical fluid solvent mixture.

doi:10.34984/SCFTP.2018.13.4.005