Cyclization of o-phenylenediamine and o-substituted Anilines with Carbon Dioxide in Supercritical State

2019, №2

сс. 31-39

Yu.M. Panov, L.V. Erkhova, A.G. Balybin, D.P. Krut'ko, D.A. Lemenovskii.

Key words: supercritical carbon dioxide, cyclization, benz-1,3-azol-2-ones, tin(II) derivatives

It was demonstrated that tin(II) 2-ethylhexanoate and tin(II) oxide are effective catalysts for the reaction of cyclization of model arylamines o-NH₂(C₆H₄)XH (X = NH, O, S, CH₂NH) in supercritical carbon dioxide with the formation of benzo-1,3-azol-2- ones and 3,4-dihydroquinazolin-2-one. Optimal conditions for these reactions were found. Possible mechanisms for these processes are proposed depending on the used catalyst.

doi:10.34984/SCFTP.2019.14.2.004

Previous paper Next paper

Cite

ГОСТ
7.0.100-2018

Панов, Ю.М. Cyclization of o-phenylenediamine and o-substituted Anilines with Carbon Dioxide in Supercritical State / Ю.М. Панов, Л.В. Эрхова, А.Г. Балыбин [и др.]. – Текст : непосредственный // Сверхкритические Флюиды: Теория и Практика.. – 2019. – Т. 14. – № 2. – С. 31-39. - DOI: 10.34984/SCFTP.2019.14.2.004

TRANSLIT

Panov, YU.M. Ciklizaciya o-fenilendiamina i o-zameshchennyh anilinov s dioksidom ugleroda v sverhkriticheskom sostoyanii / YU.M. Panov, L.V. Erhova, A.G. Balybin [i dr.]. – Tekst : neposredstvennyj // Sverhkriticheskie Flyuidy: Teoriya i Praktika.. – 2019. – Т. 14. – № 2. – S. 31-39. - DOI: 10.34984/SCFTP.2019.14.2.004

Yu.M. Panov, L.V. Erkhova, A.G. Balybin, D.P. Krut'ko, D.A. Lemenovskii Cyclization of o-phenylenediamine and o-substituted Anilines with Carbon Dioxide in Supercritical State. Sverhkriticheskie Flyuidy: Teoriya i Praktika, 2, 31-39 (2019). https://doi.org/10.34984/SCFTP.2019.14.2.004

Cyclization of o-phenylenediamine and o-substituted Anilines with Carbon Dioxide in Supercritical State

Cite

Поиск

Связаться с нами

Copied