Applied the Synthesis of Heterogeneous Catalysts by Laser Ablation of Metallic Palladium with Рdeposition on Alumina in the Supercritical Carbon Dioxid

2019, №3

сс. 64-70

E.O. Epifanov, A.G. Shubnyi, N.V. Minaev, A.O. Rybaltovskii, V.I. Yusupov, O.P. Parenago.

Key words: supercritical carbon dioxide, laser ablation, carrier, metal target, composite, catalysts, hydrogenation

An experimental setup was created to produce deposited heterogeneous catalysts by laser ablation of a metal target in the presence of various carriers in supercritical carbon dioxide (SC-CO₂). The conditions of pulsed laser exposure (wavelength, frequency, and time), SC-CO₂ medium parameters (pressure, temperature) and the configuration of experimental setup (laser, target, carrier and visual and optical control elements) were worked out. A composite consisting of Al₂O₃ with Pd particles was obtained by laser ablation of metal palladium with deposition onto γ-alumina in a SCCO₂ medium. The synthesized composite has been studied as a catalyst for liquidphase hydrogenation of di phenylacetylene and its high activity (TOF = 1.45 s^-1) and high selectivity in hydrogenation of one triple bond has been shown.

doi:10.34984/SCFTP.2019.14.3.007

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ГОСТ
7.0.100-2018

Епифанов, Е.О. Applied the Synthesis of Heterogeneous Catalysts by Laser Ablation of Metallic Palladium with Рdeposition on Alumina in the Supercritical Carbon Dioxid / Е.О. Епифанов, А.Г. Шубный, Н.В. Минаев [и др.]. – Текст : непосредственный // Сверхкритические Флюиды: Теория и Практика.. – 2019. – Т. 14. – № 3. – С. 64-70. - DOI: 10.34984/SCFTP.2019.14.3.007

TRANSLIT

Epifanov, E.O. Sintez nanesennyh geterogennyh katalizatorov pri lazernoj ablyacii metallicheskogo palladiya s osazhdeniem na oksid alyuminiya v srede sverhkriticheskogo dioksida ugleroda / E.O. Epifanov, A.G. SHubnyj, N.V. Minaev [i dr.]. – Tekst : neposredstvennyj // Sverhkriticheskie Flyuidy: Teoriya i Praktika.. – 2019. – Т. 14. – № 3. – S. 64-70. - DOI: 10.34984/SCFTP.2019.14.3.007

E.O. Epifanov, A.G. Shubnyi, N.V. Minaev, A.O. Rybaltovskii, V.I. Yusupov, O.P. Parenago Applied the Synthesis of Heterogeneous Catalysts by Laser Ablation of Metallic Palladium with Рdeposition on Alumina in the Supercritical Carbon Dioxid. Sverhkriticheskie Flyuidy: Teoriya i Praktika, 3, 64-70 (2019). https://doi.org/10.34984/SCFTP.2019.14.3.007

Applied the Synthesis of Heterogeneous Catalysts by Laser Ablation of Metallic Palladium with Рdeposition on Alumina in the Supercritical Carbon Dioxid

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