Hydroformylation of alkenes in supercritical carbon dioxide catalyzed by rhodium complexes with amidophosphite derivatives of carboranes

2012, №3

сс. 4-11

S.E. Lyubimov, E.A. Rastorguev, P.V. Petrovskii, T.A. Verbitskaya, V.N. Kalinin, V.A. Davankov

Key words: carboranes, hydroformylation, supercritical carbon dioxide, rhodium, amidophosphites

A synthesis of novel carborane-containing phosphites is carried out. Their efficiency as ligands in rhodium-catalyzed hydroformylation of alkenes in supercritical carbon dioxide (SC-CO₂) is tested. It is demonstrated that in the presence of newly synthesized carboranylamidophosphites a high alkene conversion at low catalyst loading can be achieved. An improved regioselectivity is obtained in SC-CO₂ medium compared to toluene.

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doi:10.1134/S1990793112080131

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ГОСТ
7.0.100-2018

Любимов, С.Е. Hydroformylation of alkenes in supercritical carbon dioxide catalyzed by rhodium complexes with amidophosphite derivatives of carboranes / С.Е. Любимов, Е.А. Расторгуев, П.В. Петровский [и др.]. – Текст : непосредственный // Сверхкритические Флюиды: Теория и Практика.. – 2012. – Т. 7. – № 3. – С. 4-11.

TRANSLIT

Lyubimov, S.E. Gidroformilirovanie alkenov v sverhkriticheskom diokside ugleroda, kataliziruemoe kompleksami Rh s amidofosfitnymi proizvodnymi karboranov / S.E. Lyubimov, E.A. Rastorguev, P.V. Petrovskij [i dr.]. – Sverhkriticheskie Flyuidy: Teoriya i Praktika.. – 2012. – Т. 7. – № 3. – S. 4-11.

S.E. Lyubimov, E.A. Rastorguev, P.V. Petrovskii, T.A. Verbitskaya, V.N. Kalinin, V.A. Davankov Hydroformylation of alkenes in supercritical carbon dioxide catalyzed by rhodium complexes with amidophosphite derivatives of carboranes. Sverhkriticheskie Flyuidy: Teoriya i Praktika, 3, 4-11 (2012). https://doi.org/

Hydroformylation of alkenes in supercritical carbon dioxide catalyzed by rhodium complexes with amidophosphite derivatives of carboranes

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