Quinizarin – an Effective Photocatalyst for Oxidation of Organic Sulfides in a Supercritical Carbon Dioxide Medium

2025, №2

сс. 45-58

D.A. Kletnov, V.G. Merkulov, E.A. Ivanova, M.N. Zharkov, I.V. Kuchurov, S.G. Zlotin

Key words: photocatalysis, oxidation, sulfides, quinones, supercritical carbon dioxide

Quinizarin was first used as a photocatalyst for the oxidation of organic compounds with molecular oxygen in a supercritical carbon dioxide (SC-CO₂) medium under the visible light irradiation. The choice of the catalyst was justified by the availability and high efficiency of quinizarin in comparison with structurally similar derivatives of anthraquinone: 2-nitro-1,4-dihydroxyanthraquinone and 2,3-diamino-1,4-dihydroxyanthraquinone. Carrying out photocatalytic synthesis of sulfoxides and sulfones via oxidation of organic sulfides with molecular oxygen in a SC-CO₂ medium allows to reduce its fire hazard and make it environmentally benign.

Full text (PDF)

Translated article

doi:10.1134/S1990793125701258

Полный текст статьи

Предыдущая статья Следующая статья

Цитировать

ГОСТ
7.0.100-2018

Клетнов, Д.А. Quinizarin – an Effective Photocatalyst for Oxidation of Organic Sulfides in a Supercritical Carbon Dioxide Medium / Д.А. Клетнов, В.Г. Меркулов, Е.А. Иванова [и др.]. – Текст : непосредственный // Сверхкритические Флюиды: Теория и Практика.. – 2025. – Т. 20. – № 2. – С. 45-58. - DOI: 10.34984/SCFTP.2025.20.2.002

TRANSLIT

Kletnov, D.A. Hinizarin – effektivnyj fotokatalizator okisleniya organicheskih sul'fidov v srede sverhkriticheskogo dioksida ugleroda / D.A. Kletnov, V.G. Merkulov, E.A. Ivanova [i dr.]. – Sverhkriticheskie Flyuidy: Teoriya i Praktika.. – 2025. – Т. 20. – № 2. – S. 45-58. - DOI: 10.34984/SCFTP.2025.20.2.002

D.A. Kletnov, V.G. Merkulov, E.A. Ivanova, M.N. Zharkov, I.V. Kuchurov, S.G. Zlotin Quinizarin – an Effective Photocatalyst for Oxidation of Organic Sulfides in a Supercritical Carbon Dioxide Medium. Sverhkriticheskie Flyuidy: Teoriya i Praktika, 2, 45-58 (2025). https://doi.org/10.34984/SCFTP.2025.20.2.002

Quinizarin – an Effective Photocatalyst for Oxidation of Organic Sulfides in a Supercritical Carbon Dioxide Medium

Цитировать

Спасибо. Ваши данные отправлены