2008, №3

сс. 30-38

Small-Angle Light Scattering on Density Fluctuations of Supercritical Carbon Dioxide under the Conditions of Fast Cooling

2008, №3

сс. 30-38

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D.A. Zimnyakov, A.P. Sviridov, A.N. Konovalov, V.N. Bagratashvili

Key words: scattering, supercritical media, intensity fluctuations, scattering anisotropy

The results of experimental studies of static and dynamic scattering of  laser light in CO2 under the conditions of transition from supercritical to gas phase with the  cooling rate 4 x 10-4 degree/sec are presented. It  is found that both angular light distribution and first order spectral momentum  of fluctuations of forward scattered light intensity are changed  insignificantly when critical parameter of media is changed in the interval 0 < |T/Tc - 1| ≤ 5 x 10-5. The increase of  critical parameter |T/Tc - 1| > 5 x 10-5 causes the reduction of  scattered light intensity and the rise of first order spectral momentum of  intensity fluctuations. Such behavior assumes the existence of «metastable»  ensemble of slowly changed in size scattered centers.