Dispersion Copolymerization of Methylmetacrylate and Styrol in Supercritical Dioxide Medium

2010, №2

сс. 70-79

P.S. Timashev, L.I. Krotova, D.A. Lemenovskii, V.K. Popov

Key words: supercritical carbon dioxide, methylmetacrylate, styrol, co-polymers, polymer nanocomposites

We report about thin polymer particles synthesis based on radical co-polymerization of methylmetacrylate and styrol in supercritical СO₂ medium. We utilize supercritical СO₂ soluble polydimethylsiloxan metacrylate as a dispersion agent, which allow us to produce almost monosize particles. Co-polymer spherical powder, with typical sizes about 1 micron and molecular weight M_w ~ 36000 has higher thermostability compare to similar M_w polymethylmetacrylate. We have shown the possibility of mechanical and hydrophobic co-polymer properties controlled changes with varying of monomer charge ratio.

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doi:10.1134/S199079311007016X

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ГОСТ
7.0.100-2018

Тимашев, П.С. Dispersion Copolymerization of Methylmetacrylate and Styrol in Supercritical Dioxide Medium / П.С. Тимашев, Л.И. Кротова, Д.А. Леменовский [и др.]. – Текст : непосредственный // Сверхкритические Флюиды: Теория и Практика.. – 2010. – Т. 5. – № 2. – С. 70-79.

TRANSLIT

S., P. Dispersionnaya sopolimerizaciya metilmetakrilata i stirola v sverhkriticheskom diokside ugleroda / P. S. Timashev, L. I. Krotova, D. A. Lemenovskij [i dr.]. – Sverhkriticheskie Flyuidy: Teoriya i Praktika.. – 2010. – Т. 5. – № 2. – S. 70-79.

P.S. Timashev, L.I. Krotova, D.A. Lemenovskii, V.K. Popov Dispersion Copolymerization of Methylmetacrylate and Styrol in Supercritical Dioxide Medium. Sverhkriticheskie Flyuidy: Teoriya i Praktika, 2, 70-79 (2010). https://doi.org/

Dispersion Copolymerization of Methylmetacrylate and Styrol in Supercritical Dioxide Medium

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