2012, №1

сс. 3-12

Supercritical СО2 exreactions of waste components formed in propylene epoxidation process

2012, №1

сс. 3-12

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R.A. Kayumov, A.T. Galimova, A.A. Sagdeev, A.A. Petukhov, F.M. Gumerov

Key words: styrene, phenol, methylphenylcarbinol, acetophenone, ethylbenzene, propylene glycol, molybdenum, supercritical carbon dioxide, solubility, dynamic method, description of solubility, Peng — Robinson equation

Experimental  results on solubility of the styrene, phenol, methylphenylcarbinol,  acetophenone, ethylbenzene, propylene glycol and molybdenum as a complex with  Trilon B in supercritical СO2 obtained using a dynamic (flow) method are  presented. The obtained data are described in the framework of Peng — Robinson  equation. The results of experiments on the extraction of organic components  from the waste formed in the olefin epoxidation process at Nizhnekamskneftekhim  Inc., on the analysis of extract composition, and on the testing of the extract  as an epoxidation catalyst are presented.