Synthesis of Nowel Promising Materials via Impregnation of Crosslinked Polymeric Networks with Metal Complexes in Supercritical Carbon Dioxide

2015, №3

сс. 84-88

I.O. Rybakova, A.E. Lazhko, A.V. Zolotuchina, P.S. Timashev, V.N. Bagratashvili, A.L. Maksimov, E.A. Karakhanov, O.P. Parenago

Key words: crosslinked polymeric networks, crosslinking agents, supercritical carbon dioxide, rhodium acetylacetonate, impregnation, rhodium nanosized particles

Three types of polymers — phenol-formaldehyde copolymer, polypropyleneimine and
polyamidoamine dendrimeres — are synthesized using polycondensation method.
Mesoporous polymeric networks are formed by treating two last polymers with
crosslinking agents. For the first time an impregnation of polymeric networks with
rhodium acetylacetonate in supercritical carbon dioxide is carried out and optimal
conditions are determined. Using Raman spectroscopy it is shown that metal content in
polymer networks is within the range of 0,3—2,0% mass. depending on the type of
polymer and crosslinking agent and on the crosslinking degree. By reduction of
immobilized rhodium acetylacetonate with molecular hydrogen polymer samples
including rhodium nanoparticles are obtained. According to preliminary data, these samples
possess extremely high activity as catalysts for hydrogenation of unsaturated compounds.

Translated article

doi:10.1134/S1990793116070162

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ГОСТ
7.0.100-2018

Рыбакова, И.О. Synthesis of Nowel Promising Materials via Impregnation of Crosslinked Polymeric Networks with Metal Complexes in Supercritical Carbon Dioxide / И.О. Рыбакова, А.Э. Лажко, А.В. Золотухина [и др.]. – Текст : непосредственный // Сверхкритические Флюиды: Теория и Практика.. – 2015. – Т. 10. – № 3. – С. 84-88.

TRANSLIT

Rybakova, I.O. Poluchenie novyh perspektivnyh materialov putem impregnacii sshityh polimernyh setok metallokompleksami v srede sverhkriticheskogo dioksida ugleroda / I.O. Rybakova, A.E. Lazhko, A.V. Zolotuhina [i dr.]. – Sverhkriticheskie Flyuidy: Teoriya i Praktika.. – 2015. – Т. 10. – № 3. – S. 84-88.

I.O. Rybakova, A.E. Lazhko, A.V. Zolotuchina, P.S. Timashev, V.N. Bagratashvili, A.L. Maksimov, E.A. Karakhanov, O.P. Parenago Synthesis of Nowel Promising Materials via Impregnation of Crosslinked Polymeric Networks with Metal Complexes in Supercritical Carbon Dioxide. Sverhkriticheskie Flyuidy: Teoriya i Praktika, 3, 84-88 (2015). https://doi.org/

Synthesis of Nowel Promising Materials via Impregnation of Crosslinked Polymeric Networks with Metal Complexes in Supercritical Carbon Dioxide

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