2007, №3

сс. 48-56

Extraction of Actinoids by Neutral Extragent Solutions in Supercritical and Liquid Freons

2007, №3

сс. 48-56

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V.A. Kamachev, A.Yu. Shadrin, A.A. Murzin, D.N. Shafikov

Key words: carbon dioxide, freon, supercritical fluid, Uranium, Plutonium, irradiated nuclear fuel, extraction

Supercritical freon-22 and liquid freon-134a can dissolve 11÷12 and 19÷25 vol.% of tributylphosphate (TBP), respectively, in dynamic conditions. These solutions efficiently extract nitric acid up to mole ratios [HNO3] : [TBP] from 1.5:1 to 2.3:1. The solution of TBP · nHNO3 adduct in freon-134a efficiently dissolves uranium and mixtures mimicking the irradiated nuclear fuel from reactors of VVER type.