Reactions of Ozone with Organic Substrates in Supercritical Carbon Dioxide

2007, №4

сс. 30-42

D.A. Lemenovskii, S.A. Yurin, V.V. Timofeev, V.K. Popov, V.N. Bagratashvili, Yu.E. Gorbaty, G.P. Brusova, V.V. Lunin

Key words: ozone, ozonation of organic substances, supercritical carbon dioxide (SC-CO₂), dicyclopentadiene

The new original procedure for preparative reactions of ozone with organic substrates in supercritical (SC) fluids as solvents is proposed. Reactions of ozone with o-isopropenylaniline and dicyclopentadiene as model substrates are investigated, and their products are identified using GC-MS, IR- and NMR-spectroscopies. It is demonstrated that in the case of reaction of ozone with o-isopropenylaniline SC-CO₂ not only plays the role of efficient solvent for both ozone and organic substrate, but also stabilizes ozone (prevents its decomposition) and participates in the process as a co-reactant.

Предыдущая статья Следующая статья

Цитировать

ГОСТ
7.0.100-2018

Леменовский, Д.А. Reactions of Ozone with Organic Substrates in Supercritical Carbon Dioxide / Д.А. Леменовский, С.А. Юрин, В.В. Тимофеев [и др.]. – Текст : непосредственный // Сверхкритические Флюиды: Теория и Практика.. – 2007. – Т. 2. – № 4. – С. 30-42.

TRANSLIT

Lemenovskij, D.A. Reakcii ozona s organicheskimi substratami v sverhkriticheskom diokside ugleroda / D.A. Lemenovskij, SA. YUrin, V.V. Timofeev [i dr.]. – Sverhkriticheskie Flyuidy: Teoriya i Praktika.. – 2007. – Т. 2. – № 4. – S. 30-42.

D.A. Lemenovskii, S.A. Yurin, V.V. Timofeev, V.K. Popov, V.N. Bagratashvili, Yu.E. Gorbaty, G.P. Brusova, V.V. Lunin Reactions of Ozone with Organic Substrates in Supercritical Carbon Dioxide. Sverhkriticheskie Flyuidy: Teoriya i Praktika, 4, 30-42 (2007). https://doi.org/

Reactions of Ozone with Organic Substrates in Supercritical Carbon Dioxide

Цитировать

Спасибо. Ваши данные отправлены